Method of purifying a gas containing volatile organic materials

ABSTRACT

By contacting a gas which contains vapors of volatile organic materials with an absorption liquid comprising a refined mineral oil and one or more compounds selected out of the group consisting of phthalic esters, silicic esters, phosphoric esters, carboxylic esters, alkyl benzenes, alkyl naphthalenes, and α-olefin oligomers, the volatile organic materials can be readily absorbed into the absorption liquid and thereafter effectively separated and recovered from the absorption liquid.

BACKGROUND OF THE INVENTION

The present invention relates to a method of removing volatile organic materials from a gaseous mixture of air and vapors of volatile organic materials discharged to the atmosphere either from storage tanks or during the transportation of such materials, thereby purifying the discharged gas mixture.

When volatile organic materials such as low boiling petroleum products (e.g. gasoline, naphtha, and jet fuel), low boiling liquid hydrocarbons (e.g. aliphatics, naphthenics and aromatics), and also low boiling liquid alcohols, aldehydes, ketones, and chlorine-containing organic materials are stored, charged, or transported, gaseous mixtures are formed, which are allowed to be discharged into the atmosphere.

Various methods for removing and recovering the volatile organic materials have been proposed so far to meet strict regulations for the discharge of these gaseous mixtures.

SUMMARY OF THE INVENTION

The primary object of this invention is to remove the volatile organic materials simply and effectively from such gaseous mixtures.

Another object of this invention is to recover the removed and separated volatile organic materials in high purity and in high yield by utilizing in recycle the absorption liquid which has absorbed the volatile organic materials.

Further, the above objects are accomplished by the present invention with the employment of an absorption liquid prepared by blending a mineral oil of an average molecular weight of 200 to 350 with the above-mentioned compounds in the range of 0.1 to 75% by weight of said absorption liquid. In this invention, there is provided a method of purifying gas having high absorption and separation efficiencies.

It is known that in a method of purifying gas by use of an absorption liquid having excellent efficiency in the absorption of volatile organic materials is insufficient in separating the same, and that, on the other hand, an absorption liquid having low efficiency in the absorption of volatile organic materials is superior in separation ability for the same.

The inventors have made efforts to develop an absorption liquid having excellent capability of both absorbing and separating volatile organic materials and have succeeded in providing an excellent purification method by utilizing an absorption liquid according to the present invention.

It is desired that the absorption liquid used in this method is of a high dissolving capacity for volatile organic materials, and is insoluble in water, with its kinematic viscosity of not more than 100 centistokes (symbol) cSt. at room temperature and its boiling point of not less than 250° C. at normal pressure and its freezing point of not more than -30° C.

As constituents of the absorption liquid satisfying the above requirements, there are; phthalic esters such as methyl-ethyl phthalate, diisodecyl phthalate diisodecyl phthalate, diethyl phthalate, dioctyl phthalate, didecyl phthalate, dibutyl phthalate, dimethyl phthalate, dilauryl phthalate, decyl-isooctyl phthalate, butylbenzyl phthalate, and butyl-lauryl phthalate; silicic esters such as tetraoctyl silicate and tetrannonyl silicate; and phosphoric esters such as trioctyl phosphate, tricresyl phosphate, tributyl phosphate, tributoxyethyl phosphate, trixylenyl phosphate, tricresyl-diphenyl phosphate, and octyl-diphenyl phosphate.

In addition to the above-mentioned compounds, carboxylic esters such as dioctyl adipate, dibutyl adipate, dioctyl azelate, dibutyl sebacate, dioctyl sebacate, and butyl oleate, alkyl benzenes such as n-dodecyl benzene, and isododecyl benzene, and α-olefin oligomers having an average molecular weight of 300 to 400 and a kinematic viscosity of 10 to 20 cSt. at 37.8° C. may be used.

The absorption liquid employed in this invention is prepared by blending with the aforesaid various compounds a refined mineral oil having an average molecular weight of 200 to 350, a kinematic viscosity of 5 to 20 cSt. at 37.8° C., and a boiling range of 250° to 450° C. under normal pressure in the range of 0.1 to 75% by weight of said absorption liquid. This blending ratio may be optionally varied depending on the component with which the refined mineral oil is blended, but the content of more than 75% by weight of the refined mineral oil in said absorption liquid makes it difficult to obtain high absorption and separation efficiencies at which the present invention aims.

The reason why the viscosity of the absorption liquid used in this invention is limited is that too high viscosity of the absorption liquid causes not only a noticeable decrease in absorption efficiency and large pressure drop in an absorption tower, but also a flooding when the absorption liquid is contacted with gas in counterflow in the tower, and exerts an adverse effect on the power consumed in the handling of the absorption liquid. On the other hand, too low viscosity means low molecular weight, thus high vapor pressure, and causes the absorption liquid to form an azeotropic mixture with the volatile organic materials separated from the absorption liquid in a separator and mix into the volatile organic materials to be recovered, leading to a decrease in the purity of recovered volatile organic compounds. Further, if the molecular weight of the absorption liquid is too low, the solubility of the volatile organic materials decreases greatly.

BRIEF DESCRIPTION OF THE DRAWING

FIG. 1 is a schematic diagram illustrating an embodiment of the process used to execute the method in accordance with the present invention.

Description of this embodiments is made in the attached drawing, a gasoline tank 1 is equipped with an exhaust gas pipe 2, gas mixture being discharged from the exhaust gas pipe at the time of temperature rise or gasoline charge. The gas discharged from the exhaust gas pipe 2 is introduced into an absorption tower 3. The interior of said absorption tower 3 is filled with packings such as Raschig-rings, into which said gas mixture is introduced at the bottom and the absorption liquid is flushed from the top of the tower to be contacted with said gas mixture in a counter current flow. The contact ratio of said absorption liquid and said gas in the absorption tower is in the range of 5 to 300 (kgs absorption liquid/m³ gas). The air which has had the volatile organic compounds removed is discharged from the top of the absorption tower 3 to the atmosphere through a flame arrestor (not shown). The amount of the volatile organic materials contained in the discharged air is so small that it does not contribute to photochemical smog.

The operation in the absorption tower 3 is ordinarily performed at atmospheric temperature and under atmospheric pressure, but it may also be carried out under pressure or under pressurized and cooled conditions, and further the gas mixture may be absorbed after it is subjected to pretreatment of pressurization and cooling as the case may be.

The absorption liquid which has absorbed the volatile organic materials in the absorption tower 3 is taken out of the bottom of absorption tower 3 and introduced into a separator 4, where the volatile organic materials are separated by evaporation. The absorption liquid which has had the volatile organic materials therein separated is taken out of the bottom of separator 4 and sent to the top of absorption tower 3 by a pump, thus being utilized in recycle. The volatile organic materials separated by evaporation in the separator 4 are further sent to a gasoline absorption tower 5, where they are condensed and absorbed. The gasoline in the bottom of gasoline absorption tower 5 is sent back to a gasoline storage tank, and the vapor not condensed in the gasoline absorption tower 5 is recirculated through a pipe 6 to the absorption tower 3 and removed.

It will be understood to those skilled in the art that the method in accordance with the present invention is not limited to the above-mentioned embodiment and such modifications as follows are possible without departing from the spirit and the scope of the invention. The shape of the packings packed in the absorption tower may differ from that of Raschig-ring; the structure of the absorption tower is not necessarily limited to a packed tower and a plate column or the like may be used as far as it permits a good contact effect between the gas and liquid; a distillation tower may substitute for the separator, stripping process by using an inert gas such as nitrogen may be applied in order to separate the volatile organic materials more efficiently in the separator; and a condenser may be used instead of the gasoline absorption tower.

The method according to this invention being that of absorbing gas mixtures into an absorption liquid as described above, there is no danger of explosion. According to this method, it is possible to improve separation rate without decreasing absorption efficiency of the volatile organic materials into the absorption liquid, to enhance purity and recovery rate of the volatile organic materials, and to purify the gas mixture economically almost without any loss in the absorption liquid in absorption and separation processes, because the separation of the volatile organic materials from the absorption liquid is easy and there is no anxiety of azeotropy as is the case of using kerosene or gas oil.

In addition to those features mentioned above the method of this invention has the advantage that, since well-known means are available, this method requires no special equipment to conduct the same.

Examples 1 to 9 of the method according to the invention are indicated below, wherein a gas mixture containing volatile organic materials was absorbed by various absorption liquids at 35° C. in an absorption tower filled with Raschig-rings.

On the other hand, into 200g of various absorption liquids were dissolved 1 to 5% by weight of the volatile organic materials, solutions were placed in air-tight containers, maintained at the prescribed temperature and reduced pressure under agitation and sucked for 4 minutes, and thereafter the amounts of the organic materials separated (the loss in the amounts of the solutions) were determined.

                                      EXAMPLE 1                                    __________________________________________________________________________     Absorption and separation of n-pentane (n-C5) by                               tetranonyl silicate/refined mineral oil system                                 ABSORPTION                                                                             n-C5 content                                                                           Flow rate                                                              in inlet                                                                               of inlet     Flow rate                                                                            n-C5 content                                                                          Flow rate                                    absorption                                                                             absorption                                                                           n-C5 content                                                                          of inlet                                                                             in outlet                                                                             of outlet                                                                            Absorption                             liquid  liquid                                                                               in inlet gas                                                                          gas   gas    gas   rate                                   (wt.%)  (g/min)                                                                              (mol%) (l/min)                                                                              (mol%) (l/min)                                                                              (%)                            __________________________________________________________________________     Tetranonyl                                                                             0.0     117   26.5   0.98  1.23   0.73  96.6                           silicate                                                                               1.5     121   26.5   0.90  3.19   0.68  90.8                           Tetranonyl                                                                             0.0     136   29.2   0.99  1.55   0.71  96.2                           silicate                                                                       50vol%  1.5     139   29.2   0.94  3.47   0.69  91.3                           Refined                                                                        mineral oil                                                                    50vol%  3.0     137   29.2   0.94  5.83   0.71  85.0                           Tetranonyl                                                                     silicate                                                                               0.0     137   29.2   0.99  1.31   0.71  96.8                           25vol%  1.5     134   29.2   0.99  3.39   0.73  91.5                           Refined 3.0     138   29.2   0.92  5.76   0.69  85.2                           mineral oil                                                                    75vol%                                                                         Refined 0.0     134   29.2   0.99  1.34   0.71  96.7                           mineral oil                                                                            1.5     134   29.2   0.94  3.35   0.69  91.6                                   3.0     134   29.2   0.96  5.72   0.72  85.3                           __________________________________________________________________________     SEPARATION                                                                                     pressure                                                                               50mmHg                                                                 temperature                                                                            35° C.                                                          time    4 min.                                                         n-C5 content in                                                                        Separated n-C5                                                         absorption                                                                             vs absorption                                                          liquid  liquid  Separation rate                                                (wt.%)  (wt.%)  (%)                                                    __________________________________________________________________________     Tetranonyl                                                                             1       0.29    29.0                                                   silicate                                                                               2       0.54    27.0                                                           3       0.97    32.3                                                   Tetranonyl                                                                             1       0.33    33.0                                                   silicate                                                                       50vol%                                                                                 2       0.62    31.0                                                   Refined                                                                        mineral oil                                                                    50vol%  3       1.07    35.7                                                   Tetranonyl                                                                             1       0.36    36.0                                                   silicate                                                                       25vol%                                                                                 2       0.65    32.5                                                   Refined                                                                        mineral oil                                                                    75vol%  3       1.02    34.0                                                   Refined 1       0.25    25.0                                                   mineral oil                                                                            2       0.45    22.5                                                           3       0.83    27.7                                                   __________________________________________________________________________

                                      EXAMPLe 2                                    __________________________________________________________________________     Absorption and separation of n-pentane (n-C5) by                               alkyl benzene/refined mineral oil system                                       ABSORPTION                                                                             n-C5 content                                                                           Flow rate                                                              in inlet                                                                               of inlet     Flow rate                                                                            n-C5 content                                                                          Flow rate                                    absorption                                                                             absorption                                                                           n-C5 content                                                                          of inlet                                                                             in outlet                                                                             of outlet                                                                            Absorption                             liquid  liquid                                                                               in inlet gas                                                                          gas   gas    gas   rate                                   (wt.%)  (g/min)                                                                              (mol%) (l/min)                                                                              (mol%) (l/min)                                                                              (%)                            __________________________________________________________________________             0.0     131.1 26.5   0.95  0.47   0.70  98.7                           Alkylbenzene                                                                           1.5     131.1 26.5   0.95  2.62   0.72  92.5                                   3.0     136.3 26.5   0.86  4.74   0.66  86.2                           Alkyl   0.0     134   29.2   0.99  0.82   0.71  98.0                           benzene                                                                        50vol%  1.5     130   29.2   0.93  3.12   0.68  92.2                           Refined                                                                        mineral oil                                                                    50vol%  3.0     134   29.2   1.02  5.53   0.76  85.8                                   0.0     134   29.2   0.99  1.34   0.71  96.7                           Refined 1.5     134   29.2   0.94  3.35   0.69  91.6                           Mineral oil                                                                            3.0     134   29.2   0.96  5.72   0.72  85.3                           __________________________________________________________________________                     pressure                                                                               50 mmHg                                                                temperature                                                                            35° C.                                          SEPARATION      time    4 min.                                                         n-C5 content in                                                                        Separated n-C5                                                         absorption                                                                             vs absorption                                                          liquid  liquid  Separation rate                                                (wt.%)  (wt.%)  (%)                                                    __________________________________________________________________________              2      0.41    20.5                                                   Alkyl   3       0.72    24.0                                                   benzene 4       1.19    29.8                                                   Alkyl   2       0.44    22.0                                                   benzene                                                                        50vol%                                                                                 3       0.83    27.7                                                   Refined                                                                        mineral oil                                                                    50vol%  4       1.26    31.5                                                           2       0.45    22.5                                                   Refined 3       0.83    27.7                                                   mineral oil                                                                            4       1.24    31.0                                                   __________________________________________________________________________

                                      EXAMPLE 3                                    __________________________________________________________________________     Absorption and separation of n-pentane (n-C5)                                  by dioctyl adipate/refined mineral oil system                                  ABSORPTION                                                                             n-C5 content                                                                           Flow rate                                                              in inlet                                                                               of inlet     Flow rate                                                                            n-C5 content                                                                          Flow rate                                    absorption                                                                             absorption                                                                           n-C5 content                                                                          of inlet                                                                             in outlet                                                                             of outlet                                                                            Absorption                             liquid  liquid                                                                               in inlet gas                                                                          gas   gas    gas   rate                                   (wt.%)  (g/min)                                                                              (mol%) (l/min)                                                                              (mol%) (l/min)                                                                              (%)                            __________________________________________________________________________     Dioctyl 0.0     142   26.1   0.96  1.77   0.72  95.0                           adipate 1.5     142   26.5   0.88  4.47   0.67  87.0                           Dioctyl 0.0     137   29.2   0.97  1.62   0.70  96.0                           adipate                                                                        50vol%                                                                                 1.5     137   29.2   1.01  3.31   0.74  91.7                           Refined                                                                        Mineral oil                                                                            3.0     137   29.2   0.94  5.94   0.71  84.7                           50vol%                                                                                 0.0     134   29.2   0.99  1.34   0.71  96.7                           Refined 1.5     134   29.2   0.94  3.35   0.69  91.6                           mineral oil                                                                            3.0     134   29.2   0.96  5.72   0.72  85.3                           __________________________________________________________________________                     pressure                                                                               50mmHg                                                                 temperature                                                                            35° C.                                          SEPARATION      time    4 min.                                                         n-C5 content in                                                                        Separated n-C5                                                         absorption                                                                             vs absorption                                                          liquid  liquid  Separation rate                                                (wt.%)  (wt.%)  (%)                                                    __________________________________________________________________________             1       0.34    34.0                                                   Dioctyl 2       0.65    32.5                                                   adipate 3       1.06    35.3                                                   Dioctyl 1       0.31    31.0                                                   adipate                                                                        50vol%                                                                                 2       0.59    29.5                                                   Refined                                                                        mineral oil                                                                            3       1.00    33.3                                                   50vol%                                                                                 1       0.25    25.0                                                   Refined 2       0.45    22.5                                                   mineral oil                                                                            3       0.83    27.7                                                   __________________________________________________________________________

                                      EXAMPLE 4                                    __________________________________________________________________________     Absorption and separation of benzene by                                        tetranonyl silicate/refined mineral oil system                                 ABSORPTION                                                                             Benzene con-                                                                          Flow rate                                                               tent in inlet                                                                         of inlet                                                                             Benzene con-                                                                          Flow rate                                                                            Benzene con-                                                                          Flow rate                                     absorption                                                                            absorption                                                                           tent in                                                                               of inlet                                                                             tent in                                                                               of outlet                                                                            Absorption                              liquid liquid                                                                               inlet gas                                                                             gas   outlet gas                                                                            gas   rate                                    (wt.%) (g/min)                                                                              (mol%) (l/min)                                                                              (mol%) (l/min)                                                                              (%)                             __________________________________________________________________________             0.0    89.1  10.85  3.5   0.83   3.11  93.1                            Tetranonyl                                                                             1.5    87.4  10.85  3.4   1.59   3.06  86.7                            silicate                                                                               3.0    90.9  10.85  3.4   2.23   3.14  81.3                            Tetranonyl                                                                             0.0    88.8  9.59   3.32  0.63   3.02  94.0                            silicate                                                                       50vol%                                                                                 1.5    88.8  9.59   3.33  1.03   3.04  90.2                            Refined                                                                        mineral oil                                                                    50vol%  3.0    88.8  9.59   3.33  1.59   3.06  84.8                                    0.0    86.7  9.59   3.35  0.67   3.05  93.7                            Refined 1.5    86.7  9.59   3.33  0.91   3.04  91.3                            mineral oil                                                                            3.0    86.7  9.59   3.35  1.52   3.08  85.5                            __________________________________________________________________________                      pressure  50mmHg                                                               temperature                                                                              80° C.                                       SEPARATION       time      4 min.                                                      Benzene content                                                                         Separated benzene                                                     in absorption                                                                           vs absorption                                                                            Separation                                                  liquid   liquid    rate                                                        (wt.%)   (wt.%)    (%)                                                 __________________________________________________________________________     Tetranonyl                                                                             3        0.38      12.7                                                silicate                                                                               4        0.74      18.5                                                        5        1.48      29.6                                                Tetranonyl                                                                             3        0.46      15.3                                                silicate                                                                       50vol%  4        0.88      22.0                                                Refined                                                                        mineral oil                                                                    50vol%  5        1.52      30.4                                                        3        0.35      11.7                                                Refined 4        0.70      17.5                                                mineral oil                                                                            5        1.48      29.6                                                __________________________________________________________________________

                                      EXAMPLE 5                                    __________________________________________________________________________     Absorption and separation of benzene by                                        dioctyl adipate/tetranonyl silicate/refined mineral oil system                 ABSORPTION                                                                             Benzene con-                                                                          Flow rate                                                               tent in inlet                                                                         of inlet                                                                             Benzene con-                                                                          Flow rate                                                                            Benzene con-                                                                          Flow rate                                     absorption                                                                            absorption                                                                           tent in                                                                               of inlet                                                                             tent in                                                                               of outlet                                                                            Absorption                              liquid liquid                                                                               inlet gas                                                                             gas   outlet gas                                                                            gas   rate                                    (wt.%) (g/min)                                                                              (mol%) (l/min)                                                                              (mol%) (l/min)                                                                              (%)                             __________________________________________________________________________             0.0    88.3  9.59   3.33  0.19   3.02  98.2                            Dioctyl 1.5    88.3  9.59   3.41  0.58   3.10  94.5                            adipate 3.0    88.3  9.59   3.35  0.77   3.05  92.7                                    0.0    89.1  10.85  3.5   0.83   3.11  93.1                            Tetranonyl                                                                             1.5    87.4  10.85  3.4   1.59   3.06  86.7                            silicate                                                                               3.0    90.9  10.85  3.4   2.23   3.14  81.3                            Dioctyl                                                                        adipate 0.0    87.1  9.59   3.37  0.29   3.06  97.2                            33.3vol%                                                                       Tetranonyl                                                                     silicate                                                                               1.5    87.1  9.59   3.32  0.81   3.03  92.3                            33.3vol%                                                                       Refined                                                                        mineral oil                                                                            3.0    87.1  9.59   3.37  0.99   3.08  90.6                            33.4vol%                                                                               0.0    86.7  9.59   3.35  0.67   3.05  93.7                            Refined 1.5    86.7  9.59   3.33  0.91   3.04  91.3                            mineral oil                                                                            3.0    86.7  9.59   3.35  1.52   3.08  85.5                            __________________________________________________________________________                      pressure  50mmHg                                                               temperature                                                                              30°  C.                                      SEPARATION       time      4 min.                                                      Benzene content                                                                         Separated benzene                                                     in absorption                                                                           vs absorption                                                         liquid   liquid    Separation rate                                             (wt.%)   (wt.%)    (%)                                                 __________________________________________________________________________             3        0.20       6.7                                                Dioctyl 4        0.44      11.0                                                adipate 5        0.96      19.2                                                        3        0.38      12.7                                                Tetranonyl                                                                             4        0.74      18.5                                                silicate                                                                               5        1.48      29.6                                                Dioctyl                                                                        adipate 3        0.30      10.0                                                33.3vol%                                                                       Tetranonyl                                                                     silicate                                                                               4        0.63      15.8                                                33.3vol%                                                                       Refined                                                                        mineral oil                                                                            5        1.29      25.8                                                33.4vol%                                                                               3        0.35      11.7                                                Refined 4        0.70      17.5                                                mineral oil                                                                            5        1.48      29.6                                                __________________________________________________________________________

                                      EXAMPLE 6                                    __________________________________________________________________________     Absorption and separation of cyclohexane (CH) by                               alkyl naphthalene/refined mineral oil system                                   ABSORPTION                                                                             CH content                                                                            Flow rate                                                               in inlet                                                                              of inlet                                                                             CH content                                                                            Flow rate                                                                            CH content                                                                            Flow rate                                     absorption                                                                            absorption                                                                           in inlet                                                                              of inlet                                                                             in outlet                                                                             of outlet                                                                            Absorption                              liquid liquid                                                                               gas    gas   gas    gas   rate                                    (wt%)  (g/min)                                                                              (mol%) (l/min)                                                                              (mol%) (l/min)                                                                              (%)                             __________________________________________________________________________             0      148   15.2   3.99  1.81   3.45  89.7                            Alkyl   2      148   15.2   3.92  1.91   3.39  89.1                            naphthalene                                                                            4      148   15.2   3.98  2.11   3.45  88.0                            Alkyl   0      148   15.2   4.01  0.68   3.42  96.2                            naphthalene                                                                    25vol%                                                                                 2      148   15.2   3.96  0.96   3.39  94.6                            Refined                                                                        mineral oil                                                                            4      148   15.2   3.93  1.47   3.38  91.7                            75vol%                                                                                 0      148   15.2   3.90  0.51   3.32  97.9                            Refined 2      148   15.2   3.96  0.87   3.39  95.1                            mineral oil                                                                            4      148   15.2   3.92  1.36   3.37  92.8                            __________________________________________________________________________                      pressure                                                                               20mmHg                                                                 temperature                                                                            50° C.                                         SEPARATION       time    4 min.                                                        CH content in                                                                           Separated CH                                                          absorption                                                                              vs absorption                                                         liquid   liquid  Separation rate                                               (wt.%)   (wt.%)  (%)                                                   __________________________________________________________________________             2        0.36    18.0                                                  Alkyl   3        0.68    22.7                                                  naphthalene                                                                            4        1.11    27.8                                                  Alkyl   2        0.23    11.5                                                  naphthalene                                                                    25vol%                                                                                 3        0.53    17.7                                                  Refined                                                                        mineral oil                                                                            4        0.95    23.8                                                  75vol%                                                                                 2        0.13     6.5                                                  Refined 3        0.41    13.7                                                  mineral oil                                                                            4        0.85    21.2                                                  __________________________________________________________________________

                                      EXAMPLE 7                                    __________________________________________________________________________     Absorption and separation of methanol by                                       trioctyl phosphate/refined mineral oil system                                  ABSORPTION                                                                             Methanol con-                                                                          Flow rate                                                              tent in inlet                                                                          of inlet                                                                             Methanol con-                                                                          Flow rate                                                                            Methanol con-                                                                          Flow rate                                  absorption                                                                             absorption                                                                           tent in of inlet                                                                             tent in of outlet                                                                            Absorption                           liquid  liquid                                                                               inlet gas                                                                              gas   outlet gas                                                                             gas   rate                                 (wt.%)  (g/min)                                                                              (mol%)  ( /min)                                                                              (mol%)  ( /min)                                                                              (%)                          __________________________________________________________________________             0.0     124   19.7    1.25  1.42    1.02  94.1                         Trioctyl                                                                               1.5     127   19.7    1.22  3.38    1.01  86.1                         phosphate                                                                              3.0     122   19.7    1.26  5.09    1.07  78.1                         Trioctyl                                                                               0.0     130   19.7    1.20  1.61    0.98  93.3                         phosphate                                                                      50vol%                                                                                 1.5     130   19.7    1.23  3.48    1.02  85.3                         Refined                                                                        mineral oil                                                                            3.0     130   19.7    1.23  5.23    1.04  77.5                         50vol%                                                                                 0.0     133   19.7    1.25  2.47    1.03  89.7                         Refined 1.5     133   19.7    1.22  4.19    1.02  82.2                         mineral oil                                                                            3.0     133   19.7    1.27  6.47    1.09  71.8                         __________________________________________________________________________                      pressure  50mmHg                                                               temperature                                                                              35° C.                                       SEPARATION       time      4 min.                                                      Methanol content                                                                        Separated methanol                                                    in absorption                                                                           vs absorption                                                                            Separation                                                  liquid   liquid    rate                                                        (wt.%)   (wt.%)    (%)                                                 __________________________________________________________________________             1        0.42      42.0                                                Trioctyl                                                                               2        0.88      44.0                                                phosphate                                                                              3        1.53      51.0                                                Trioctyl                                                                               1        0.54      54.0                                                phosphate                                                                      50vol%                                                                                 2        1.15      57.5                                                Refined                                                                        mineral oil                                                                            3        1.90      63.3                                                50vol%                                                                                 1        0.57      57.0                                                Refined 2        1.28      64.0                                                mineral oil                                                                            3        2.11      70.3                                                __________________________________________________________________________

                                      EXAMPLE 8                                    __________________________________________________________________________     Absorption and separation of methylethylketone (MEK) by                        polyolefin/mineral oil system                                                  ABSORPTION                                                                             MEK content                                                                            Flow rate                                                              in inlet                                                                               of inlet                                                                             MEK content                                                                            Flow rate                                                                            MEK content                                                                            Flow rate                                  absorption                                                                             absorption                                                                           in inlet                                                                               of inlet                                                                             in outlet                                                                              of outlet                                                                            Absorption                           liquid  liquid                                                                               gas     gas   gas     gas   rate                                 (wt.%)  (g/min)                                                                              (mol%)  (l/min)                                                                              (mol%)  (l/min)                                                                              (%)                          __________________________________________________________________________             0.0     128   12.2    1.22  0.77    1.08  94.4                         Polyolefin                                                                             1.5     126   12.2    1.22  1.54    1.09  88.7                                 3.0     125   12.2    1.23  2.28    1.11  83.2                         Polyolefin                                                                             0.0     131   12.2    1.26  0.74    1.11  94.6                         50vol%                                                                                 1.5     133   12.2    1.21  1.49    1.08  89.1                         Refined                                                                        mineral oil                                                                    50vol%  3.0     130   12.2    1.23  2.04    1.10  85.0                                 0.0     136   12.2    1.22  0.66    1.08  95.2                         Refined 1.5     136   12.2    1.24  1.50    1.11  89.0                         mineral oil                                                                            3.0     136   12.2    1.22  1.96    1.09  85.6                         __________________________________________________________________________                      pressure 50mmHg                                                                temperature                                                                             80° C.                                        SEPARATION       time     4 min.                                                       MEK content in                                                                          Separated MEK                                                         absorption                                                                              vs absorption                                                         liquid   liquid   Separation rate                                              (wt.%)   (wt.%)   (%)                                                  __________________________________________________________________________             3        0.21     7.0                                                  polyolefin                                                                             4        0.65     16.3                                                         5        1.28     25.6                                                 Polyolefin                                                                             3        0.19     6.3                                                  50vol%  4        0.59     14.8                                                 Refined 5        1.19     23.8                                                 mineral oil                                                                    50vol%                                                                                 3        0.16     5.3                                                  Refined 4        0.50     12.5                                                 mineral oil                                                                            5        1.02     20.4                                                 __________________________________________________________________________

                                      EXAMPLE 9                                    __________________________________________________________________________     Absorption and separation of 1.2-di-chloroethane (EDC) by                      dibutyl phthalate/refined mineral oil system                                   ABSORPTION                                                                             EDC content                                                                            Flow rate                                                              in inlet                                                                               of inlet      Flow rate                                                                            EDC content                                                                            Flow rate                                  absorption                                                                             absorption                                                                           EDC content                                                                            of inlet                                                                             in outlet                                                                              of outlet                                                                            Absorption                           liquid  liquid                                                                               in inlet gas                                                                           gas   gas     gas   rate                                 (wt.%)  (g/min)                                                                              (mol%)  (l/min)                                                                              (mol%)  (l/min)                                                                              (%)                          __________________________________________________________________________      . - 0.0 164 9.33 1.22 0.48 1.11 95.3                                          Dibutyl 1.5     160   9.33    1.22  0.93    1.12  90.9                         phthalate                                                                              3.0     164   9.33    1.23  1.60    1.13  84.2                         Dibutyl 0.0     150   9.33    1.26  0.66    1.15  93.5                         phthalate                                                                      50vol%                                                                                 1.5     148   9.33    1.21  1.04    1.11  89.8                         Refined                                                                        mineral oil                                                                    50vol%  3.0     148   9.33    1.23  1.74    1.13  82.8                                 0.0     136   9.33    1.22  0.96    1.12  90.6                         Refined 1.5     136   9.33    1.24  1.38    1.14  86.4                         mineral oil                                                                            3.0     136   9.33    1.22  2.04    1.13  79.8                         __________________________________________________________________________                      pressure 20mmHg                                                                temperature                                                                             50° C.                                        SEPARATION       time     4 min.                                                       EDC content in                                                                          Separated EDC                                                         absorption                                                                              vs absorption                                                         liquid   liquid   Separation rate                                              (wt.%)   (wt.%)   (%)                                                  __________________________________________________________________________             3        0.47     15.7                                                 Dibutyl 4        1.04     26.0                                                 phthalate                                                                              5        1.72     34.4                                                 Dibutyl 3        0.69     23.0                                                 phthalate                                                                      50vol%  4        1.25     31.3                                                 Refined                                                                        mineral oil                                                                    50vol%  5        2.02     40.4                                                         3        0.78     26.0                                                 Refined 4        1.33     33.3                                                 mineral oil                                                                            5        2.15     43.0                                                 __________________________________________________________________________ 

What we claim is:
 1. A method of purifying a gaseous mixture containing air and vapors of volatile organic materials selected from the group consisting of low boiling petroleum products (e.g. gasoline, naphtha and jet fuel), low boiling liquid products (e.g. aliphatics, naphthenics and aromatics), and also low boiling liquid alcohols, aldehydes, ketones, and chlorine-containing organic materials which comprises contacting said gaseous mixture with an absorption liquid prepared by blending a refined mineral oil with at least one compound selected from the group consisting of methyl ethyl phthalate, diethyl phthalate, dioctyl phthalate, didecyl phthalate, dibutyl phthalate, dimethyl phthalate, dilauryl phthalate, decyl isooctyl phthalate, butyl benzyl phthalate and butyl lauryl phthalate; tetraoctyl silicate and tetranonyl silicate; trioctyl phosphate, tricresyl phosphate, tributyl phosphate, tributoxyethyl phosphate, trixylenyl phosphate, tricresyl diphenyl phosphate, and octyl diphenyl phosphate; dioctyl adipate, dibutyl adipate, dioctyl azelate, dibutyl sebacate, dioctyl sebacate, and butyl oleate; n-dodecyl benzene and isododecyl benzene; α-olefin oligomers having an average molecular weight of 300 to 400 and a kinematic viscosity of 10 to 20 cSt, at 37.8° C,said mineral oil having an average molecular weight of 200 to 350, a kinematic viscosity of 5 to 20 cSt at 37.8° C, and boiling range of 250° C to 450° C under normal pressure, and absorbing said volatile organic materials therefrom into said absorption liquid.
 2. The method according to claim 1, wherein the content of said refined mineral oil in the absorption liquid is within the range of 0.1 to 75% by weight.
 3. The method according to claim 1, wherein the contact ratio of said absorption liquid and said gaseous mixture in the absorption tower is in the range of 5 to 300 (Kgs absorption liquid/m³ gas). 